2023年内蒙古自治区大气PM2.5中重金属及类金属健康风险评估

Health risk assessment of heavy metals and metalloids in atmospheric PM2.5 from Inner Mongolia Autonomous Region in 2023

  • 摘要:
    背景 内蒙古自治区地域广阔、生态环境多样,各地大气污染特征存在显著差异,现有研究缺乏涵盖全区的系统性研究与风险评估。
    目的 评估2023年内蒙古自治区大气细颗粒物(PM2.5)中9种重金属及类金属元素经呼吸途径对人群所产生的健康风险。
    方法 2023年每月10—16日在内蒙古自治区12个盟(市)设监测点,逐月进行大气PM2.5采样,分析质量浓度(后简称为浓度)特征及变化规律。采用美国环保署的健康风险评估模型对重金属元素铍(Be)、镉(Cd)、铬(Cr)、汞(Hg)、铅(Pb)、锰(Mn)、镍(Ni)以及类金属元素锑(Sb)、砷(As)的非致癌和致癌风险进行评估。
    结果 2023年内蒙古自治区共计检测有效PM2.5样品1206份,其中内蒙古自治区及鄂尔多斯市、乌海市和阿拉善盟的PM2.5年均浓度均超过35 μg·m−3的国家限值,且各盟(市)浓度呈现明显的季节差异,冬季最高,春季次之,夏秋季最低;鄂尔多斯市全年PM2.5浓度中位数高于全区其他盟(市)。健康风险方面,各盟(市)检测的9种元素的非致癌风险均低于1,处于可接受范围,但Mn、Cr和As元素的非致癌风险值较高,其中鄂尔多斯市Mn非致癌风险为7.74×10−1、Cr非致癌风险为2.97×10−2,赤峰市As非致癌风险为2.34×10−3。As、Cd、Cr和Ni的致癌风险值介于1×10−9~1×10−5,属可接受水平。不同人群的健康风险呈现年龄差异,老年人群非致癌风险值和致癌风险值均居首位。
    结论 尽管内蒙古自治区大气PM2.5中重金属及类金属元素致癌风险和非致癌风险总体在可接受范围内,但Mn、As和Cr三种元素对老年人群体健康的潜在威胁需给予特别关注。健康风险评估数据显示,鄂尔多斯市和赤峰市相较于其他地区呈现显著的高值特征。建议针对各盟(市)监测点的实际情况,实施常态化的长期监测,并采取具有针对性的大气质量管理策略,以保障公众健康。

     

    Abstract:
    Background The Inner Mongolia Autonomous Region is a vast area with a wide array of ecological environments, resulting in considerable regional variations in air pollution characteristics. Current research is limited by a scarcity of systematic, region-wide studies and risk assessments.
    Objective To assess the health risks associated with inhalation exposure to nine heavy metal and metalloid elements in atmospheric fine particulate matter (PM2.5) for the population of the Inner Mongolia Autonomous Region.
    Methods From the 10th to the 16th of each month throughout 2023, atmospheric PM2.5 samples were collected at designated monitoring sites in 12 leagues (cities) across the Inner Mongolia Autonomous Region to analyze the characteristics and trends in concentration. The health risk assessment model developed by the United States Environmental Protection Agency was employed to evaluate both the non-carcinogenic and carcinogenic risks associated with the heavy metal elements beryllium (Be), cadmium (Cd), chromium (Cr), hydrargyrum (Hg), plumbum (Pb), manganese (Mn), and nickel (Ni) and the metalloid elements stibium (Sb) and arsenic (As).
    Results In 2023, a total of 1206 valid PM2.5 samples were analyzed from the Inner Mongolia Autonomous Region. The annual average PM2.5 concentrations in Inner Mongolia, as well as in the cities of Ordos, Wuhai, and the Alxa League, all exceeded the national limit of 35 μg·m−3. The PM2.5 concentrations across the leagues (cities) exhibited a clear seasonal variation, peaking in winter, followed by spring, and reaching a minimum in summer and autumn. The median PM2.5 concentration in Ordos throughout the year was higher than that in the other leagues (cities) of the region. Concerning health risks, the non-carcinogenic risks associated with the 9 elements detected in each league (city) were all below 1, indicating acceptable levels. However, the non-carcinogenic risk values for Mn, Cr, and As were relatively high; specifically, Ordos City displayed the highest non-carcinogenic risk values for Mn (7.74×10−1) and Cr (2.97×10−2), while Chifeng City recorded the highest value for As (2.34×10−3). The carcinogenic risk values for As, Cd, Cr, and Ni fell within the range of 1×10−9 to 1×10−5, representing an acceptable level. The health risks varied with age, and the elderly residents faced the highest non-carcinogenic and carcinogenic health risks.
    Conclusion While the carcinogenic and non-carcinogenic risks from heavy metals and metalloids within atmospheric PM2.5 in the Inner Mongolia Autonomous Region are generally within acceptable limits, the potential risks that Mn, As, and Cr pose to the health of elderly people warrants particular attention, and Ordos and Chifeng cities exhibit notably higher health risks among other areas. It is recommended that regular, long-term monitoring be conducted, taking into account the specific conditions at monitoring sites across each league (city), and that targeted air quality management strategies be implemented to protect public health.

     

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